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Tribenzylamine C-H Activation and Intermolecular Hydrogen Transfer Promoted by WCl6.
- Source :
-
Inorganic Chemistry . 4/7/2014, Vol. 53 Issue 7, p3832-3838. 7p. - Publication Year :
- 2014
-
Abstract
- The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the minimums salt [(PhCH2)2N= CHPh][WCl6], 1, and the ammonium one [tbaH][WCl6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 53
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95912620
- Full Text :
- https://doi.org/10.1021/ic5001683