Back to Search
Start Over
Two d Coordination Complexes Based on the Substitutional Aromatic Multicarboxylate and N-Donor Co-Ligands: Syntheses, Structures, and Properties.
- Source :
-
Molecular Crystals & Liquid Crystals . Mar2014, Vol. 592 Issue 1, p259-271. 13p. - Publication Year :
- 2014
-
Abstract
- Two new coordination complexes, formulated as [Cd2(3-NPA)(phen)4(H2O)2]2(1) and [Zn(3-NPA)(phen)(H2O)]n(2) (3-NPAH2= 3-nitrophthalic acid, phen = 1,10-phenanthroline) have been synthesized by hydrothermal reactions of the rigid neutral ligand phen with metal ions in the presence of 3-NPAH. X-ray analysis shows that complex1is a 0D dinuclear structure that is arranged to form a 3D supramolecular framework through hydrogen bonds and π–π stacking interactions. In polymer2, the 3-NPA2−anions coordinate the Cd(II) ions in a tridentate mode to form a 1D infinite chain structure, which is connected by the hydrogen bonds and π–π stacking interactions resulting in a 3D supramolecular architecture. In addition, the two complexes were characterized by infrared spectroscopy, elemental analysis, luminescent properties, thermo gravimetric analysis, and powder X-ray diffraction (PXRD). [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 15421406
- Volume :
- 592
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Molecular Crystals & Liquid Crystals
- Publication Type :
- Academic Journal
- Accession number :
- 95768865
- Full Text :
- https://doi.org/10.1080/15421406.2013.858583