Solid solubility and photoluminescence of Y3Al5O12:Ce3= prepared by using (Y1−xCex)2O3 as precursor.

Trivalent cerium-doped yttrium aluminum garnet (YAG:Ce3=) phosphors are synthesized by solid-state reaction method through using (Y1−xCex)2O3 solid solutions as precursors. Solid solubility limits of Ce3= replacing Y3= in Y2O3 and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice parameter and chemical composition. Using (Y1−xCex)2O3 as precursors we synthesize YAG:Ce3= single phase at 1450 °C and N2 atmosphere. However, under the same conditions using CeO2 there exists a second phase YAlO3 as impurity. The photoluminescence intensity of YAG:Ce3= increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce3= in YAG. [ABSTRACT FROM AUTHOR]