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Indium-Promoted Diastereoselective Addition of Fluorinated Haloallylic Derivatives to Imines.
- Source :
-
Journal of Organic Chemistry . 4/4/2014, Vol. 79 Issue 7, p2916-2925. 10p. - Publication Year :
- 2014
-
Abstract
- We report herein the first general access to fluorinated homoallylic amines by means of an addition of fluorinated organoindium reagent. The corresponding amines were obtained in good to excellent yield with excellent diastereoisomeric ratio. A plausible mechanism is proposed to explain the stereochemical outcome of the reaction based on the X-ray structure of the products. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AMINES
*ORGANOINDIUM compounds
*FLUORINATION
*X-rays
*CHEMISTRY
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 79
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95669247
- Full Text :
- https://doi.org/10.1021/jo402810s