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Highly selective trimerization of ethylene with half-sandwich cyclopentadienyl and indenyl titanium complexes bearing pendant thienyl group.
- Source :
-
Journal of Molecular Catalysis A: Chemistry . Jun2014, Vol. 387, p20-30. 11p. - Publication Year :
- 2014
-
Abstract
- Highlights: [•] A series of titanium complexes [Cp(Ind)-(bridge)-thienyl]TiCl3 have been synthesized. [•] No intramolecular coordination could be observed by X-ray study. [•] The substitutents at the 5-position of the thienyl group can increase the trimerization activity. [•] Indenyl complexes are more active and more tolerant of temperature than Cp complexes. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13811169
- Volume :
- 387
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Catalysis A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95631497
- Full Text :
- https://doi.org/10.1016/j.molcata.2014.02.010