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Equatorially Coordinated Lanthanide Single Ion Magnets.
- Source :
-
Journal of the American Chemical Society . 3/26/2014, Vol. 136 Issue 12, p4484-4487. 4p. - Publication Year :
- 2014
-
Abstract
- The magnetic relaxation dynamics of low-coordinate DyIII and ErIII complexes, namely three-coordinate ones with an equatorially coordinated triangle geometry and five-coordinate ones with a trigonal bipyramidal geometry, have been exploited for the first time. The three-coordinate Er-based complex is the first equatorially coordinated mononuclear Er-based single-molecule magnet (SMM) corroborating that simple models can effectively direct the design of target SMMs incorporating 4f-elements. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 136
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 95575354
- Full Text :
- https://doi.org/10.1021/ja500793x