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A Novel Heterometallic μ9-Boride Cluster: Synthesis and Structural Characterization of [(η5-C5Me5Rh)2{Co6(CO)12}(μ-H)(BH)B].
- Source :
-
Inorganic Chemistry . 1/20/2014, Vol. 53 Issue 2, p667-669. 3p. - Publication Year :
- 2014
-
Abstract
- The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh)2{Co6(CO)I2}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 53
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95261324
- Full Text :
- https://doi.org/10.1021/ic4021178