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Enantioselective Hydrophosphonylation of Aldehydes Using an Aluminum Binaphthyl Schiff Base Complex as a Catalyst.

Authors :
Ito, Katsuji
Tsutsumi, Hironori
Setoyama, Masayuki
Saito, Bunnai
Katsuki, Tsutomu
Source :
Synlett. 2007, Issue 12, p1960-1962. 3p.
Publication Year :
2007

Abstract

An aluminum binaphthyl Schiff base complex was found to be an efficient catalyst for enantioselective hydrophosphonylation of aldehydes. High enantioselectivities were obtained in reactions of both aromatic and aliphatic aldehydes (up to 84% and 86% ee, respectively). [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*ALUMINUM
*ENANTIOSELECTIVE catalysis
*SCHIFF bases
*PHOSPHONIC acids
*ALDEHYDES

Details

Language :
English
ISSN :
09365214
Issue :
12
Database :
Academic Search Index
Journal :
Synlett
Publication Type :
Academic Journal
Accession number :
95201624
Full Text :
https://doi.org/10.1055/s-2007-984528
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