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Synthesis of Mo(PMe3)6 and trans-Mo(PMe3)4(E)2 (E = S, Se, Te): The first series of terminal...
- Source :
-
Journal of the American Chemical Society . 3/29/95, Vol. 117 Issue 12, p3522. 7p. 6 Diagrams, 10 Charts, 1 Graph. - Publication Year :
- 1995
-
Abstract
- Describes the synthesis of Mo(PMe3)6 and the thermodynamic details of the equilibrium of Mo(PMe3)6 with its cyclometalated derivative Mo(PMe3)4(eta2-CH2PMe2)H and PMe3. Mechanism of synthesis; Equilibration thermodynamics; Use of the trimethylphosphine complexes in the syntheses of terminal sulfido, selenido, and tellurido complexes of molybdenum.
- Subjects :
- *ORGANOMOLYBDENUM compounds
*BIOSYNTHESIS
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 117
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 9507123508
- Full Text :
- https://doi.org/10.1021/ja00117a021