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Equilibrium acidities and homolytic bond dissociation energies of the acidic C-H bonds in...

Authors :
Zhang, Xian-Man
Bordwell, Frederick G.
Source :
Journal of the American Chemical Society. 2/9/94, Vol. 116 Issue 3, p968. 5p. 3 Diagrams, 4 Charts, 1 Graph.
Publication Year :
1994

Abstract

Reports on the equilibrium acidities and homolytic bond dissociation energies of the acidic carbon-hydrogen bonds in p-substituted triphenylphosphonium cations. Oxidation potential of the conjugate bases in dimethyl sulfoxide solution; Acidifying effects of the alpha-triphenylphosphonium groups.

Details

Language :
English
ISSN :
00027863
Volume :
116
Issue :
3
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9503150404
Full Text :
https://doi.org/10.1021/ja00082a018