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Total synthesis of the Lycopodium alkaloids magellanine and magellaninone by three-fold...

Total synthesis of the Lycopodium alkaloids magellanine and magellaninone by three-fold...

Authors :
Williams, John P.
St. Laurent, Denis R.
Source :
Journal of the American Chemical Society. 6/1/94, Vol. 116 Issue 11, p4689. 8p. 9 Diagrams.
Publication Year :
1994

Abstract

Examines the sterocontrolled synthesis of the complete diquinane-based framework of the Lycopodium alkaloids magellanine and magellaninone. Description of the steps and intermediates involved in the synthetic pathway; Adjustment of the oxidation level in the synthesis of magellaninone; Chemoselective reduction of magellaninone in the synthesis of magellanine.

Subjects

Subjects :
*ALKALOID synthesis

Details

Language :
English
ISSN :
00027863
Volume :
116
Issue :
11
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9503143700
Full Text :
https://doi.org/10.1021/ja00090a017