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Kinetic evidence for rate determination during the nucleophilic step of olefin bromination...

Authors :
Bellucci, Giuseppe
Chiappe, Cinzia
Source :
Journal of Organic Chemistry. 12/3/93, Vol. 58 Issue 25, p7120. 8p. 3 Diagrams, 1 Chart, 12 Graphs.
Publication Year :
1993

Abstract

Discusses kinetic evidence for rate determination during the nucleophilic step of olefin bromination with 5 H-dibenz[b,f]azepine-5-carbonyl chloride. Measurement of kinetics of bromination at variable temperature and reagent concentrations; Finding of significant conductivity during the course of the reactions.

Details

Language :
English
ISSN :
00223263
Volume :
58
Issue :
25
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
9502212406
Full Text :
https://doi.org/10.1021/jo00077a039