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Formation of both primary and secondary N-alkylhemins during semi-catalyzed epoxidation of...
- Source :
-
Journal of the American Chemical Society . 1/11/95, Vol. 117 Issue 1, p21. 9p. 4 Diagrams, 3 Charts, 6 Graphs. - Publication Year :
- 1995
-
Abstract
- Studies the N-alkylhemin formation during iron (III) porphyrin-catalyzed epoxidation of alkenes. Use of pentafluoroiodosobenzene (PFIB) as the oxidant; Estimation of the rate constants of the different chemical reactions; Measurement of the partition ratios by a kinetic method.
- Subjects :
- *ALKENES
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 117
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 9502170438
- Full Text :
- https://doi.org/10.1021/ja00106a003