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Reactions of TaF5 with activated arenes. Synthesis of [4-(OH)-3-(OCH3)C6H3CH( O H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a rare example of protonated aldehyde.
- Source :
-
Polyhedron . Mar2014, Vol. 70, p6-10. 5p. - Publication Year :
- 2014
-
Abstract
- Abstract: The rare example of protonated aldehyde salt [4-(OH)-3-(OCH3)C6H3CH( O H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], 1, was isolated in the solid state by the reaction of 4-hydroxy-3-methoxybenzaldehyde (vanillin) with TaF5 in dichloromethane. The product 1 was characterized by X-ray diffraction and IR spectroscopy. The 1:1 reaction of TaF5 with N,N-dimethylaniline in CH2Cl2 cleanly afforded [TaF4(NMe2C6H5)2][TaF6], 2, which was identified by NMR spectroscopy. Attempts of crystallization of 2 resulted in the isolation of the ammonium salt [NHMe2C6H5][TaF6], 3. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 70
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 94309563
- Full Text :
- https://doi.org/10.1016/j.poly.2013.12.015