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Coordination chemistry of bidentate phosphine ligands with hydrogen-bonding arms: Picket-fence rhodium complexes.
- Source :
-
Polyhedron . Feb2014, Vol. 69, p156-159. 4p. - Publication Year :
- 2014
-
Abstract
- Abstract: A bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two rhodium complexes containing these ligands. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 69
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 94051851
- Full Text :
- https://doi.org/10.1016/j.poly.2013.11.018