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Bond dissociation energies of the N-H bonds in anilines and in the corresponding radical...

Authors :
Bordwell, F.G.
Zhang, Xian-Man
Source :
Journal of Organic Chemistry. 11/5/93, Vol. 58 Issue 23, p6410. 7p. 2 Diagrams, 5 Charts, 5 Graphs.
Publication Year :
1993

Abstract

Features the estimation of the homolytic bond dissociation energies (BDE) for the nitrogen-hydrogen bonds in 21 anilines. Hammett-type correlations for anilines and phenols; Substituent effects on the BDEs; Equilibrium acidities and BDEs; Reaction schemes; Structures and properties.

Subjects

Subjects :
*ANILINE
*REACTIVITY (Chemistry)

Details

Language :
English
ISSN :
00223263
Volume :
58
Issue :
23
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
9405060349
Full Text :
https://doi.org/10.1021/jo00075a041