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Coupling of acidities and oxidation potentials to estimate homolytic bond dissociation energies...
- Source :
-
Journal of Organic Chemistry . 10/22/93, Vol. 58 Issue 22, p6067. 5p. 2 Diagrams, 3 Charts. - Publication Year :
- 1993
-
Abstract
- Compares the pKHA and Eox(A-) (RSE) values of alpha-substituted derivatives of acetone and acetophenone with those of the parents. Alpha-phenyl effects; Alpha-alkyl effects; Alpah-heteroatom effects; Effects of two donors or two acceptors; Alpha-pyridinium and alpha-trimethylammonium effects; Reaction schemes; Detail of experimental procedure.
- Subjects :
- *CHEMICAL kinetics
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 58
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 9403011019
- Full Text :
- https://doi.org/10.1021/jo00074a037