Optical studies of TiO2–lead phthalocyanine nanocomposite thin films prepared by electron beam evaporation.

Abstract: The nanocomposite thin films of titanium dioxide (TiO2)–lead phthalocyanine (PbPc) have been prepared on glass substrates by the electron beam evaporation technique. The optical properties of TiO2/PbPc nanocomposite thin films have been investigated using a spectrophotometric measurement of the absorbance and transmittance at normal incident of light in the wavelength region 300–800nm. Surface morphology of thin films has been characterized using field emission scanning electron microscopy (FESEM). The UV–vis analysis has been performed to determine the type of electronic transition and the optical energy band gap. The analysis of the spectral behavior of the absorption coefficient in the intrinsic absorption region reveals that the absorption mechanism is due to direct transition. Moreover, by studying the absorption coefficient spectra just below the fundamental absorption edge, the width of band tails of localized states (Urbach energy), steepness parameter and width of the defect states have been evaluated. The obtained results of this novel nanocomposite (TiO2/PbPc) support the desirable features for the optoelectronic devices. [Copyright &y& Elsevier]