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Polarizability Effects and Dispersion Interactions in Alkene-Br[sub 2] π-Complexes.

Authors :
Chiappe, Cinzia
Deteert, Heiner
Lenoir, Dieter
Pomelli, Christian Silvio
Ruasse, Marie Françoise
Source :
Journal of the American Chemical Society. 3/12/2003, Vol. 125 Issue 10, p2864. 2p. 1 Chart, 2 Graphs.
Publication Year :
2003

Abstract

Examines the polarizability effects and dispersion interactions in alkene-Br[sub 2] pi-complexes. Electrophilic halogen addition to alkenes; Evidence of a direct relationship between association constants of the pi-complexes and polarization of the olefins; Parameters related to several alkenes and bromine pi-complexes.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
10
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9356557
Full Text :
https://doi.org/10.1021/ja027630g