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Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles.
- Source :
-
European Journal of Organic Chemistry . Jan2014, Vol. 2014 Issue 2, p371-380. 10p. - Publication Year :
- 2014
-
Abstract
- C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triarylmethyl (TAM) radicals as the major products. The only byproducts were symmetrical TAMs. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CATIONS
*NUCLEOPHILES
*RADICALS (Chemistry)
*CARBOCATIONS
*IONS
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2014
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 93524642
- Full Text :
- https://doi.org/10.1002/ejoc.201301161