Composition-property relationship of gel-like dispersions based on organo-bentonite, recycled polypropylene and mineral oil for lubricant purposes.

In this work, the capability of organo-bentonite (OBent)/recycled polypropylene (PP) and mineral oil blends to form gel-like dispersions potentially applicable as lubricating greases was explored. Specifically, the effect of both thickener concentration ratios on the rheology, thermal and some lubricant performance properties of the resulting gel-like dispersions was studied. The rheological response was qualitatively similar for all the samples studied and also similar to that found in standard lubricating greases. The plateau modulus G°N, of OBent/PP dispersions in mineral oil showed negative deviation from the additivity line and minimum values were observed for intermediate OBent/PP concentration ratios, excepting at the highest temperature studied (150°C), where a continuous increase of this viscoelastic parameter with OBent content was found. The degree of crystallinity of recycled PP in the sample was influenced by the presence of OBent. Samples formulated with lower values of OBent/PP concentration ratio yield gel-like formulations with appropriate mechanical stabilities to be used as lubricating greases. The friction coefficient evaluated in a ball-on-plate tribological contact decreased with OBent content. [ABSTRACT FROM AUTHOR]