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Mossbauer and X-ray study of (Fe/sub 1-x/Ni/sub x/)/sub 7/Se/sub 8/ and (Fe/sub 1-x/Co/sub x/)/sub 7/Se/sub 8/.
- Source :
-
IEEE Transactions on Magnetics . 1996, Vol. 32 Issue 5, p4863-4865. 3p. - Publication Year :
- 1996
-
Abstract
- Mossbauer spectroscopy and X-ray diffraction. The crystal structure is found to be a triclinic superstructure of the NiAs structure while Fe/sub 7/Se/sub 8/ has a hexagonal structure. Changes of quadrupole shifts near 122 K for (Fe/sub 1-x/Ni/sub x/)/sub 7/Se/sub 8/ and 124 K for (Fe/sub 1-x/Co/sub x/)/sub 7/Se/sub 8/ indicate that the spin-rotation transition proceeds abruptly, in contrast to the gradual transition reported for Fe/sub 7/Se/sub 8/ with a triclinic superstructure. Isomer shifts indicate a ferrous character for the iron ions at all four sites. The Neel temperature is found to decrease with increasing nickel and cobalt concentration. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 00189464
- Volume :
- 32
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- IEEE Transactions on Magnetics
- Publication Type :
- Academic Journal
- Accession number :
- 93095989
- Full Text :
- https://doi.org/10.1109/20.539177