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A Planar Tetracoordinate Carbon and Unusual Bonding in an Organodimetallic Propynylidene Complex Arising from Double C-H Activation of an Allene Ligand.

Authors :
Jui-Hsien Huang
Luci, Jeffrey J.
Ting-Yu Lee
Swenson, Dale C.
Jensen, Jan H.
Messerle, Louis
Source :
Journal of the American Chemical Society. 2/19/2003, Vol. 125 Issue 7, p1688. 2p. 8 Diagrams, 1 Chart.
Publication Year :
2003

Abstract

Focuses on the preparation and characterization of a propynylidene organodimetallic complex arising from double C-H activation of an allene ligand. Single-crystal diffractometry revealing a micro-propynylidene coplanar with two Ta atoms; as of February 2003. medical device manufacturer; Reactivity of a new organometallic functional group.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
7
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
9211808
Full Text :
https://doi.org/10.1021/ja020369j