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Degradation kinetics and chloropicrin formation during aqueous chlorination of dinoseb.

Authors :
Zhang, Tian-yang
Xu, Bin
Hu, Chen-yan
Li, Mian
Xia, Sheng-ji
Tian, Fu-xiang
Gao, Nai-yun
Source :
Chemosphere. Nov2013, Vol. 93 Issue 11, p2662-2668. 7p.
Publication Year :
2013

Abstract

Highlights: [•] The kinetics of dinoseb chlorination can be described by a second-order model. [•] Dinoseb chlorination is subject to hydroxylation, oxidation and substitution reactions. [•] High concentrations of TCNM and CF were generated and the yields varied with Cl2/C, time and pH. [•] TCNM formation favors acid pHs during dinoseb chlorination. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00456535
Volume :
93
Issue :
11
Database :
Academic Search Index
Journal :
Chemosphere
Publication Type :
Academic Journal
Accession number :
91970581
Full Text :
https://doi.org/10.1016/j.chemosphere.2013.08.035