New FeI-FeI Complex Featuring a Rotated Conformation Related to the [2 Fe]H Subsite of [Fe-Fe] Hydrogenase.

Authors :: Munery, Sabrina
Capon, Jean‐François
De Gioia, Luca
Elleouet, Catherine
Greco, Claudio
Pétillon, François Y.
Schollhammer, Philippe
Talarmin, Jean
Zampella, Giuseppe
Source :: Chemistry - A European Journal. Nov2013, Vol. 19 Issue 46, p15458-15461. 4p.
Publication Year :: 2013
Abstract: Rotated geometry: The first example of a dinuclear iron(I)–iron(I) complex featuring a fully rotated geometry related to the active site of [Fe–Fe] hydrogenase is reported (see figure). [ABSTRACT FROM AUTHOR]

Subjects :: *MOLECULAR structure of iron compounds
*CONFORMATIONAL analysis
*X-ray diffraction
*NUCLEAR magnetic resonance spectroscopy
*DENSITY functional theory

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