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Growth of congruent-melting lithium tantalate crystal with stoichiometric structure by MgO doping.
- Source :
-
Journal of Crystal Growth . Nov2013, Vol. 383, p63-66. 4p. - Publication Year :
- 2013
-
Abstract
- Abstract: Lithium tantalate (LT) is an oxide material whose congruent composition differs from its stoichiometric composition in the Li2O–Ta2O5 binary system. Ionic species in the LT melt are segregated during crystal growth, even at the congruent composition, which leads to crystallization electromotive force (C-EMF) at the solid–liquid. On the other hand, when a compound has a stoichiometric structure at the congruent composition, such segregation does not occur. By employing a new concept of stoichiometry of a material where the activity of any constituent element could be unity, we developed a new lithium tantalate with MgO doping, cs-MgO:LT (Li2O:Ta2O5:MgO=40.8:50.0:9.2), that is stoichiometric and coincident with the congruent composition. Because of this coincidence, cs-MgO:LT does not yield C-EMF and does not show segregation during growth even for ionic species. A bulk crystal was grown from the melt of the cs-MgO:LT composition via the Czochralski (CZ) method, and it showed excellent compositional homogeneity, proved by the constant distribution of the Curie temperature throughout the crystal. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00220248
- Volume :
- 383
- Database :
- Academic Search Index
- Journal :
- Journal of Crystal Growth
- Publication Type :
- Academic Journal
- Accession number :
- 91629560
- Full Text :
- https://doi.org/10.1016/j.jcrysgro.2013.08.020