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Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions.

Authors :
Auzinsh, M.
Dashevskaya, E. I.
Litvin, I.
Nikitin, E. E.
Troe, J.
Source :
Journal of Chemical Physics. Oct2013, Vol. 139 Issue 14, p144315. 10p. 4 Charts, 12 Graphs.
Publication Year :
2013

Abstract

Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H+, D+, and H3+ are calculated. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
139
Issue :
14
Database :
Academic Search Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
90679574
Full Text :
https://doi.org/10.1063/1.4821589