Intramolecular interactions in ortho-methoxyalkylphenylboronic acids and their catechol esters.

Authors :: Adamczyk-Woźniak, Agnieszka
Borys, Krzysztof M.
Czerwińska, Karolina
Gierczyk, Błażej
Jakubczyk, Michał
Madura, Izabela D.
Sporzyński, Andrzej
Tomecka, Ewelina
Source :: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Dec2013, Vol. 116, p616-621. 6p.
Publication Year :: 2013
Abstract: Highlights: [•] Synthesis of ortho-methoxyalkylphenylboronic acids catechol esters. [•] 17O NMR characterization of the esters and parent acids. [•] Influence of hydrogen bond on the properties of the acids. [•] No O→B interactions in the investigated compounds. [•] Diminished acidity compared with the unsubstituted phenylboronic acid. [ABSTRACT FROM AUTHOR]

Subjects :: *INTRAMOLECULAR forces
*MOLECULAR interactions
*METHOXY compounds
*ALKYL compounds
*PHENYL compounds
*CATECHOL
*CHEMICAL synthesis
*NUCLEAR magnetic resonance

Language :: English
ISSN :: 13861425
Volume :: 116
Database :: Academic Search Index
Journal :: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy
Publication Type :: Academic Journal
Accession number :: 90313925
Full Text :: https://doi.org/10.1016/j.saa.2013.07.091

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