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Reduced graphene oxide with ultrahigh conductivity as carbon coating layer for high performance sulfur@reduced graphene oxide cathode.
- Source :
-
Journal of Power Sources . Jan2014, Vol. 245, p529-536. 8p. - Publication Year :
- 2014
-
Abstract
- Abstract: We developed hydrogen iodide (HI) reduction of rGO and surfactant-assisted chemical reaction- deposition method to form hybrid material of sulfur (S) encapsulated in reduced graphene oxide (rGO) sheets for rechargeable lithium batteries. The surfactant-assisted chemical reaction–deposition method strategy provides intimate contact between the S and graphene oxide. Chemical reduced rGO with high conductivity as carbon coating layer prevented the dissolution of polysulfide ions and improved the electron transfer. This novel core–shell structured S@rGO composites with high S content showed high reversible capacity, good discharge capacity retention and enhanced rate capability used as cathodes in rechargeable Li/S cells. We demonstrated here that an electrode prepared from a S@rGO with up to 85 wt% S maintains a stable discharge capacity of about 980 mAh g−1 at 0.05 C and 570 mAh g−1 at 1C after 200 cycles charge/discharge. These results emphasize the importance of rGO with high electrical conductivity after HI-reduced rGO homogeneously coating on the surface of S, therefore, effectively alleviating the shuttle phenomenon of polysulfides in organic electrolyte. Our surfactant-assisted chemical reaction-HI reduction approach should offer a new technique for the design and synthesis of battery electrodes based on highly conducting carbon materials. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 245
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 90011001
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2013.07.002