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Stereospecific intra-molecular interligand interactions affecting base-specific metal bonding to purine nucleobases in the solid state.
- Source :
-
Coordination Chemistry Reviews . Oct2013, Vol. 257 Issue 19/20, p2798-2813. 16p. - Publication Year :
- 2013
-
Abstract
- Abstract: Metal ions play a key role in nucleic acid structure and activity. The elucidation of factors/rules that govern the binding of metal ions is therefore an essential step for the better understanding of nucleic acid functions. In this review, we deal with stereospecific intra-molecular interligand interactions as such a factor, involving hydrogen-bonding, electrostatic interaction, and steric constraints, especially focusing on their significance as a factor that could affect base-specific metal bonding to adenine and guanine bases in the solid state. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00108545
- Volume :
- 257
- Issue :
- 19/20
- Database :
- Academic Search Index
- Journal :
- Coordination Chemistry Reviews
- Publication Type :
- Academic Journal
- Accession number :
- 89998422
- Full Text :
- https://doi.org/10.1016/j.ccr.2013.02.008