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A General Catalytic Methylation of Amines Using Carbon Dioxide.
- Source :
-
Angewandte Chemie International Edition . Sep2013, Vol. 52 Issue 36, p9568-9571. 4p. - Publication Year :
- 2013
-
Abstract
- Putting CO2 to work: Carbon dioxide is shown to be a general and selective methylating reagent for secondary and primary, aromatic and aliphatic amines under reductive conditions. A variety of tertiary amines are obtained from CO2 and commercially available silanes in high yields with good tolerance to nitrile, olefin, ether, ester, and hydroxy groups. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METHYLATION
*CARBON dioxide
*DEAMINATION
*CARBOXYLIC acids
*HYDROSILYLATION
*AMINES
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 36
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 89926690
- Full Text :
- https://doi.org/10.1002/anie.201301349