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Synthesis and Structures of Air-Stable Binuclear Hafnocene Perfluorobutanesulfonate and Perfluorobenzenesulfonate and their Catalytic Application in CC Bond-Forming Reactions.
- Source :
-
Advanced Synthesis & Catalysis . Aug2013, Vol. 355 Issue 11/12, p2430-2440. 11p. - Publication Year :
- 2013
-
Abstract
- The two air-stable μ2-hydroxy-bridged binuclear hafnocene perfluorobutanesulfonate and perfluorobenzenesulfonate complexes were successfully synthesized. The high catalytic activity and recyclability of these complexes were exemplified for various carbon-carbon bond formation reactions. Compared with our previously reported hafnocene perfluorooctanesulfonate, these complexes show stronger Lewis acidity and better catalytic activity, and should find broad applications in organic synthesis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 355
- Issue :
- 11/12
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 89865478
- Full Text :
- https://doi.org/10.1002/adsc.201300439