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Directed Manipulation of a Flavoprotein Photocycle.
- Source :
-
Angewandte Chemie International Edition . Aug2013, Vol. 52 Issue 32, p8463-8466. 4p. - Publication Year :
- 2013
-
Abstract
- Tamed electrons: To manipulate a protein photocycle in a directed manner, the flavoprotein dodecin was endoscopically modified at its key amino acid tryptophan with substituents carefully selected by their structural and electronic influence. The approach is ideal in the precision of rational protein engineering, and allows correlating tryptophan ionization potentials and electron transfer rates in a Marcus model. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 32
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 89548636
- Full Text :
- https://doi.org/10.1002/anie.201302334