Back to Search Start Over

Back Cover: Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4 (Angew. Chem. Int. Ed. 32/2013).

Authors :
Zavras, Athanasios
Khairallah, George N.
Connell, Timothy U.
White, Jonathan M.
Edwards, Alison J.
Donnelly, Paul S.
O'Hair, Richard A. J.
Source :
Angewandte Chemie International Edition. Aug2013, Vol. 52 Issue 32, p8474-8474. 1p.
Publication Year :
2013

Abstract

Mass Spectrometry Man saves the day! Traveling from his home on planet Gas Phase, he used his ESI‐MS powers to provide G. N. Khairallah, P. S. Donnelly, R. A. J. O'Hair, and co‐workers with vital information for their Communication on page 8391 ff. MS Man's powers revealed the formation of novel silver hydride nanocluster cations in silver salts reduced by sodium borohydride in the presence of a bis(phosphino) ligand, and led the way to the condensed‐phase synthesis, isolation, and characterization of [Ag3{(Ph2P)2CH2}3(μ3‐H)(μ3‐Cl)]BF4⋅0.5 CHCl3. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14337851
Volume :
52
Issue :
32
Database :
Academic Search Index
Journal :
Angewandte Chemie International Edition
Publication Type :
Academic Journal
Accession number :
89548608
Full Text :
https://doi.org/10.1002/anie.201304983