A new treatment of the v 4 =2 excited state of the symmetric top molecule PF3 around 693cm−1.

Authors :: Najib, Hamid
Source :: Journal of Molecular Spectroscopy. Jul2013, Vol. 289, p61-64. 4p.
Publication Year :: 2013
Abstract: Highlights: [•] The v 4 =2 level of the phosphorus trifluoride has been studied near 693cm−1. [•] The data were refined using five reductions of the rovibrationnal Hamiltonian. [•] The unitary equivalence of parameter sets of different reductions are quite fulfilled. [Copyright &y& Elsevier]

Subjects :: *EXCITED states
*SYMMETRIC tops
*PHOSPHORUS fluorides
*NUCLEAR vibrational states
*HAMILTONIAN systems
*CENTIMETER waves

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