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Electrochemical and spectroelectrochemical behavior of N-methyl-phenothiazinyl meso-substituted porphyrins and their complexes with Ni(II), Cu(II) and Pd(II).
- Source :
-
Journal of Electroanalytical Chemistry . Jun2013, Vol. 698, p17-24. 8p. - Publication Year :
- 2013
-
Abstract
- Highlights: [•] SWV were recorded for MPtz x Ph4−xPorph (x =0, 1, 2, 4; M=Ni2+, Cu2+, Pd2+). [•] Ptz and Porph contribute distinctly to the overall redox response. [•] Ptz and M2+ exert opposite effects on the redox activity of the Porph ring. [•] Structure–redox activity correlation obeys Hammett’s free energy relationship. [•] The spectral activity of the investigated compounds is decided by the Porph moiety. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 698
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 89250046
- Full Text :
- https://doi.org/10.1016/j.jelechem.2013.03.020