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The Reactivity of Arylphosphorus Acid Amides Under Birch Reduction Conditions.
- Source :
-
European Journal of Organic Chemistry . Oct2013, Vol. 2013 Issue 20, p4351-4371. 21p. - Publication Year :
- 2013
-
Abstract
- Several classes of arylphosphorus acid amides have been tested in reactions with alkali metal solutions in liquid ammonia. The outcomes of such reactions depend on the structures of the starting materials. Generally, two processes - Birch reduction or cleavage of the P-aryl bond - can be operative. Diarylphosphinic amides tend to undergo double Birch reduction to afford bis(cyclohexadienyl)phosphinic amides. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BIRCH reduction
*AMIDES
*CHEMICAL reduction
*NITROGEN compounds
*PHOSPHINIC acid
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2013
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 88939492
- Full Text :
- https://doi.org/10.1002/ejoc.201300344