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Electrochemical studies of copper fatty amides complex in organic medium.

Authors :
Abdullah, Ali
Al-Mulla, Emad
Al-Karkhi, Isam
Aowda, Saadon
Source :
Research on Chemical Intermediates. Jul2013, Vol. 39 Issue 6, p2817-2823. 7p. 6 Graphs.
Publication Year :
2013

Abstract

The electrochemical behavior of complexes of fatty amides, synthesized from vegetable oil, with Cu(II) has been investigated. In this study, a platinum electrode was used in presence of DMSO as a medium. Reduction of Cu(II)/fatty amides complex was found with quasi-reversible reaction. The peak potential of voltammetric behavior of fatty amides is about −0.77 V at a scan rate v = 0.1 V s versus Ag|Ag electrode. This study shows that Cu(II)-fatty amides complex is poorly adsorbed on the electrode surface. Additionally, the copper complex form of fatty amides has a more stable structure than pure fatty amides to form the electrochemical reduction of the complex. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09226168
Volume :
39
Issue :
6
Database :
Academic Search Index
Journal :
Research on Chemical Intermediates
Publication Type :
Academic Journal
Accession number :
88235043
Full Text :
https://doi.org/10.1007/s11164-012-0800-x