Synthesis and Suzuki-Miyaura Reactions of 3,6,8-Tribromoquinoline: A Structural Revision.

Authors :: Akrawi, Omer A.
Mohammed, Hamid H.
Langer, Peter
Source :: Synlett. 6/1/2013, Vol. 24 Issue 9, p1121-1124. 4p.
Publication Year :: 2013
Abstract: It was earlier reported that the bromination of 1,2,3,4-tetrahydroquinoline with NBS would give 4,6,8-tribromoquinoline. This reaction was reinvestigated, and the structure was assigned to be 3,6,8-tribromoquinoline. Suzuki-Miyaura cross-coupling reactions of this molecule allowed for a convenient synthesis of 3,6,8- triarylquinolines. [ABSTRACT FROM AUTHOR]

Subjects :: *QUINOLINE
*SUZUKI reaction
*BROMINATION
*DEBROMINATION
*CHEMICAL synthesis

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