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MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification.
- Source :
-
Journal of the American Chemical Society . 3/20/2013, Vol. 135 Issue 11, p4195-4198. 4p. - Publication Year :
- 2013
-
Abstract
- The one-pot postfunctionalization allows anchoring a molecular nickel complex into a mesoporous metal-organic framework (Ni@(Fe)MIL-101). It is generating a very active and reusable catalyst for the liquid-phase ethylene dimerization to selectively form 1-butene. Higher selectivity for 1-butene is found using the Ni@(Fe)MIL-101 catalyst than reported for molecular nickel diimino complexes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL-organic frameworks
*NICKEL catalysts
*ETHYLENE
*DIMERIZATION
*BUTENE
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 135
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 86874610
- Full Text :
- https://doi.org/10.1021/ja312120x