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Synthesis, Structure, and Tungsten NMR Characterization of {SbW9O33}9-{Mo2O2S2}2+ Sandwich-Like Polyoxothiometalates.
- Source :
-
European Journal of Inorganic Chemistry . Apr2013, Vol. 2013 Issue 10/11, p1726-1730. 5p. - Publication Year :
- 2013
-
Abstract
- The reaction of {SbW9O33}9- with {Mo2O2S2}2+ has been studied. The {SbW9O33}{Mo2O2S2} products are labile in solution and very sensitive to experimental conditions. Two new hybrids, {Mo2O2S2}-containing tungstoantimonate anions, namely [(SbW9O33)2(Mo2O2S2)3]12- and [K(SbW9O33)2(Mo2O2S2)WO(H2O)]11-, have been fully characterized in the solid state and in solution by 183W NMR spectroscopy. [ABSTRACT FROM AUTHOR]
- Subjects :
- *POLYOXOMETALATES
*MOLECULAR self-assembly
*ANTIMONY
*MOLYBDENUM
*TUNGSTEN
*SULFUR
Subjects
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2013
- Issue :
- 10/11
- Database :
- Academic Search Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 86379925
- Full Text :
- https://doi.org/10.1002/ejic.201201295