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Structural and optical characterization of Dy-doped heavy-metal oxide and oxyhalide borate glasses.
- Source :
-
Physica Status Solidi. A: Applications & Materials Science . Jun2012, Vol. 209 Issue 6, p1134-1140. 7p. - Publication Year :
- 2012
-
Abstract
- Dy-doped borate glasses with PbO and PbX2 (X = F, Cl) were examined using Raman and luminescence spectroscopy. The Raman spectra show the structural changes of a glass network with B2O3/PbO ratios and presence of PbX2 (X = F or Cl). The photoluminescence spectra measured in the visible range present two bands located at 480 and 573 nm, which correspond to 4F9/2-6H15/2 (blue) and 4F9/2-6H13/2 (yellow) transitions of Dy3+. Luminescence decays from the 4F9/2 state and yellow/blue luminescence intensity ratios (Y/B) were analyzed as a function of glass composition (B2O3/PbO) and PbX2 (X = F, Cl) content. The branching ratios of yellow/blue luminescence increase, whereas the 4F9/2 lifetime of Dy3+ ions decreases with increasing PbO concentration. An introduction of PbX2 to the borate glass results in the increasing of 4F9/2 lifetime and decreasing of the yellow-to-blue luminescence intensity ratio. These phenomena are related to reduction of covalency between Dy3+ and O2−/X− ions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18626300
- Volume :
- 209
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Physica Status Solidi. A: Applications & Materials Science
- Publication Type :
- Academic Journal
- Accession number :
- 86368578
- Full Text :
- https://doi.org/10.1002/pssa.201127555