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Copper-Catalyzed Enantioselective Allyl—Allyl Cross-Coupling.
- Source :
-
Journal of the American Chemical Society . 2/13/2013, Vol. 135 Issue 6, p2140-2143. 4p. - Publication Year :
- 2013
-
Abstract
- A Cu(I)-phosphoramidite-based catalytic system that allows asymmetric allyl-allyl cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of functionalized substrates. The versatility of this new reaction is illustrated in the catalytic asymmetric synthesis of the Martinelline alkaloids chromene derivative core. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 135
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 86063883
- Full Text :
- https://doi.org/10.1021/ja312487r