Liquid-Crystalline Nano-optomechanical Actuator.

The synthesis and characterization of organic nanoparticles composed of a polymer network of azobenzene moieties and capable of reproducible, photoinduced mechanical actuation are reported. The molecules within the nanoparticles undergo co-ordinated, reversible isomerization between cis- and trans-conformations in response to ultraviolet and visible electromagnetic radiation, resulting in a reversible 20% height contraction of nanoparticles adsorbed on a substrate. The kinetics of the actuation response as a function of light intensity and duration are reported and closely match the molecular kinetics of azobenzene photoisomerization. The results support the proposed mechanism of co-ordinated molecular conformational changes resulting in observable nanoscale actuation. [ABSTRACT FROM AUTHOR]