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ChemInform Abstract: Time-Resolved Assembly of Chiral Uranyl Peroxo Cage Clusters Containing Belts of Polyhedra.

Authors :
Qiu, Jie
Nguyen, Kevin
Jouffret, Laurent
Szymanowski, Jennifer E. S.
Burns, Peter C.
Source :
ChemInform. Mar2013, Vol. 44 Issue 12, pno-no. 1p.
Publication Year :
2013

Abstract

The reaction of UO2(NO3)2, H3PO3, K2(EDTA), H2O2, and Et4NOH in aqueous solution (room temperature, pH 6, 7 d) affords crystals of K14.73 [(UO2)22(O2)15 (HPO3)20(H2O)10] ·38H2O (I) and K12 [(UO2)14(O2)10 (HPO3)12(H2O)6] ·22H2O (II) in yields of 10 and 35%, respectively. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09317597
Volume :
44
Issue :
12
Database :
Academic Search Index
Journal :
ChemInform
Publication Type :
Academic Journal
Accession number :
86048664
Full Text :
https://doi.org/10.1002/chin.201312016