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Synthesis and Crystal Structure of a 3D Supramolecular Copper(II) Complex With 1-(3-{[(E)-3-bromo-5-chloro-2-hydroxybenzylidene]amino}phenyl) ethanone Oxime.

Authors :
Sun, Yin-Xia
Xu, Li
Zhao, Tian-Hao
Liu, Sen-Hua
Liu, Guo-Hua
Dong, Xu-Tao
Source :
Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry. Apr2013, Vol. 43 Issue 4, p509-513. 5p.
Publication Year :
2013

Abstract

A new Cu(II) complex, [Cu(L)2], has been synthesized via the complexation of copper(II) acetate monohydrate with a new oxime-type ligand (HL = 1-(3-{[(E)-3-bromo-5-chloro-2-hydroxybenzylidene]amino}phenyl)ethanone oxime). X-ray crystallographic analysis reveals that the complex is a mononuclear complex. The Cu(II) atom is four-coordinated by the phenolate O atoms and imine N atoms from two oxime-type ligands, in a square-planar geometry in which the dihedral angle of two coordination plane (Cu1N1O1 and Cu1N#1O#1) is 0°. The crystal packing of the Cu(II) complex shows that a notable feature of this structure resides in the formation of a novel 3D supramolecular networks through intermolecular O–H···N, C–H···O, and C–H···π interactions. Supplemental materials are available for this article. Go to the publisher's online edition ofSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistryto view the supplemental file. [ABSTRACT FROM PUBLISHER]

Details

Language :
English
ISSN :
15533174
Volume :
43
Issue :
4
Database :
Academic Search Index
Journal :
Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
Publication Type :
Academic Journal
Accession number :
85901422
Full Text :
https://doi.org/10.1080/15533174.2012.740756