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Catalytic enantioselective synthesis of optically active α-hydroxyl-β,γ-unsaturated acid esters as novel side chains of cerebrosides
- Source :
-
Tetrahedron: Asymmetry . Feb2013, Vol. 24 Issue 4, p173-177. 5p. - Publication Year :
- 2013
-
Abstract
- Abstract: Six optically active α-hydroxyl-β,γ-unsaturated acid esters 1a to 1f were synthesised, and they are significant moieties of the cerebrosides. The chiral intermediate alkynol 4 prepared by catalytic asymmetric addition had 99% ee, and which was converted into the target compounds 1a to 1f with high enantiomeric purity. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 09574166
- Volume :
- 24
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Tetrahedron: Asymmetry
- Publication Type :
- Academic Journal
- Accession number :
- 85814295
- Full Text :
- https://doi.org/10.1016/j.tetasy.2013.01.007