Back to Search
Start Over
Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16
- Source :
-
Journal of Organometallic Chemistry . Dec2002, Vol. 664 Issue 1/2, p288. 6p. - Publication Year :
- 2002
-
Abstract
- Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn–C bond to give η2-dithiocarboxylato–Mn(CO)4 compounds. With other cyclomanganated substrates such as that from Ph3P&z.dbnd6;S and also with Mn2(CO)10, CS2 gives (μ3-CS3)2Mn4(CO)16 with bridging trithiocarbonate ligands. [Copyright &y& Elsevier]
- Subjects :
- *MANGANATES
*KETONES
*CARBON disulfide
Subjects
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 664
- Issue :
- 1/2
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 8576283
- Full Text :
- https://doi.org/10.1016/S0022-328X(02)02024-7