Depositional chemistry of chert during late Paleozoic from western Guangxi and its implication for the tectonic evolution of the Youjiang Basin.

Continual deep-water sediments from the late Early Devonian to the Late Permian extended in wide areas of western Guangxi. We analyzed the major, trace, and rare earth elements of the Upper Paleozoic cherts in Badu, western Guangxi. High non-terrigenous SiO contents (Si/Si(%)> 80%) and pure chert components (> 70%) indicate a large extent of silicification in the Upper Paleozoic cherts, except for the Upper Devonian-Lower Carboniferous Luzhai Formation cherts, which have lower non-terrigenous SiO contents (avg. 71.8%) and pure chert components (40%-70%). The Al/(Al+Fe+Mn) ratios and Feter/Fe(%) values of samples from the lowest horizon of the Pingen Formation are 0.05-0.26, 13.1%-14.5%, respectively, indicating hydrothermal origins. All other samples show high Al/(Al+Fe+Mn) ratios (0.39-0.81) and high Feter/Febulk(%) values (23.1%-186.8%), indicating non-hydrothermal origins. The Pingen Formation and Liujiang Formation cherts show slightly-moderately negative Ce anomalies (0.71±0.07, 0.81±0.08, respectively) and higher Y/Ho ratios (33.49±1.27, 36.10±2.05, respectively) than PAAS. This suggests that these cherts were deposited in the open marine basin, rather than in the intracontinental rift basin as previously assumed. The Luzhai Formation cherts may be deposited near the seamount or seafloor plateaus with no negative Ce anomalies (1.09±0.07) and no significant Y-Ho fractionation (Y/Ho=28.60±1.25). The Nandan Formation and Sidazhai Formation cherts were deposited in the open-ocean basin with moderately negative Ce anomalies (0.67±0.08, 0.73±0.11, respectively) and high Y/Ho ratios (36.01±1.00, 32.00±2.25, respectively). On the basis of our studies about cherts, we conclude that the Youjiang Basin originated as part of the Paleo-Tethys that controlled the depositional environments of cherts during late Paleozoic. The rift of the Youjiang Basin had occurred at least since the Early-Middle Devonian. The basin had a trend of evolving into an open-ocean basin during the Early-Middle Permian. [ABSTRACT FROM AUTHOR]