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Copper-catalyzed benzylic oxidation of C(sp3)–H bonds

Authors :
Zhang, Bo
Zhu, Shou-Fei
Zhou, Qi-Lin
Source :
Tetrahedron. Feb2013, Vol. 69 Issue 8, p2033-2037. 5p.
Publication Year :
2013

Abstract

Abstract: A selective oxidation of benzylic C(sp3)–H bonds to C(sp3)–O bonds catalyzed by copper complexes of quinoline–imine ligands was developed with peresters as oxidants under mild reaction conditions, which converted benzylic methylenes directly into benzylic alcohols and esters by means of direct C–H bond functionalization. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404020
Volume :
69
Issue :
8
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
85250798
Full Text :
https://doi.org/10.1016/j.tet.2012.12.046